We represent a heat engine and a heat pump cycle in
a minimalist abstract format as in the following diagrams. In both cases there
are two temperature reservoirs TH and TL, with TH >
TL.
In the case of a heat engine heat QH is
extracted from the high temperature source TH, part of that heat is
converted to work W done on the surroundings, and the rest is rejected to the
low temperature sink TL. The opposite occurs for a heat pump, in
which work W is done on the system in order to extract heat QL from
the low temperature source TL and "pump" it to the
high temperature sink TH. Notice that the thickness of the line
represents the amount of heat or work energy transferred.
We now present two statements of the Second Law of
Thermodynamics, the first regarding a heat engine, and the second regarding a
heat pump. Neither of these statements can be proved, however have never been
observed to be violated.
The Kelvin-Planck Statement: It is impossible to construct a device which
operates on a cycle and produces no other effect than the transfer of heat from
a single body in order to produce work.
We prefer a less formal description of this
statement in terms of a boat extracting heat from the ocean in order to produce
its required propulsion work:
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